Are local and 1 kpc distant Cosmic Background Radiation Temperatures the same?
Sydney Leach
Laboratoire d'Etude
du Rayonnement et de la Matière en Astrophysique, CNRS-UMR 8112, Observatoire
de Paris-Meudon, 5 place Jules Janssen, 92195 - Meudon,
The most accurate determination of the
Cosmic Background Radiation (CBR) temperature Tg
has been carried out by the orbiting observatory Cosmic Radiation Explorer
(COBE), which therefore measures its local value at about 1 AU from the Sun.
Measurement of the CBR temperature Tg(CN) from interstellar CN absorption
provides values of Tg
in several clouds within 1 kpc. Published data on
interstellar CN absorption shows that Tg(CN) is slightly greater than the standard
cosmological CBR temperature, Tg(COBE) = 2.725 ± 0.001 K, determined by
the COBE satellite, even when the effects of local excitation of CN, mainly by
electron collisions, are taken into account. One way of dealing with this
discrepancy is to consider whether the local and distant values of Tg
could be different. If one discounts
this possibility then other factors must be considered. A source of possible
error, not previously considered, in the determination of Tg(CN) from
interstellar CN absorption is proposed. This concerns the intrinsic assumption
of the validity of using Hönl-London rotational line
intensity factors to determine the rotational components of the oscillator
strengths of the CN B2S+ - X2S+
(0,0) band R(0), R(1) and P(1) lines.
The difference between the Tg(COBE) and Tg(CN)
values are used to estimate the maximum
corrections, a few percent, to the ratio of the line strengths and to the ratio
of the Hönl-London factors. Fluorescence lifetime
data are shown to give similar values for the corrections as well as providing
evidence for intramolecular coupling between the
relevant B2S+ state rotational levels and close-lying
levels of the A2P state, this being responsible for
rendering the standard Hönl-London factors invalid
[1].
[1] S.Leach, Can.J.Chem., in press (2004,
special memorial issue for Gerhard Herzberg).