N. Doslic, J. Mavri and J. Stare
R. Boskovic Institute, Zagreb,Croatia
National Institut of Chemistry, Ljubljana, Slovenia
Laser control of a proton transfer reaction in a small model system
embedded in a condensed phase environment is investigated. The two--dimensional
model comprises those features of the multi--dimensional potential energy
surface of picolinici acid
N-oxides which are most relevant for the isomerization reaction. The
influence of the remaining intramolecular coordinates as well as of a possible
environment is described by a spectral density within the reduced
density matrix approach. Different forms of the driving infrared
laser pulse are explored putting emphasis on their capability for competing
successfully with relaxation processes. The reaction dynamics is characterized
by calculating the nonlinear optical response nonperturbatively in the
driving field.
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